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Be sure not to confuse wavelength and frequency 8 The speed of light is 30 10 m/s The exponent is positive The value of n is never zero The values of l and ml include zero Do not confuse velocity (v) and frequency (n )

(1473a)

B With two equations and three variables (x;", x, , and T), fixing one of the variables allows solution of Eqs (1472) for the remaining two Since In yi, rather than yi, is a more natural thermodynamic function, application of Eqs (1472) often proceeds from the rearrangements:

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For conditions of constant pressure, or when pressure effects are negligible, binary LLE is conveniently displayed on a solubility diagram, a plot of T vs xl Figure 1412 shows binary solubility diagrams of three types The first diagram [Fig 1412(a)] shows curves (binodal curves) that define an "island" They represent the compositions of coexisting phases: curve UAL for the a! phase (rich in species 2), and curve UBL for the phase (rich in species 1) Equilibrium compositions x;" and xf at a particular T are defined by the intersections of a horizontal tie line with the binodal curves Temperature TL is a lower consolute temperature, or

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11 C The outer s electrons are not present in most transition metal ions 12 D This is part of the Heisenberg uncertainty principle 13 E The four electrons in the oxygen 2p orbitals are arranged with one pair and two unpaired electrons with parallel spins This makes the oxygen atom paramagnetic This arrangement is due to Hund s rule 14 A The Pauli exclusion principle restricts the number of electrons that can occupy a single orbital 15 B The d orbitals are shielded more efficiently than the s orbitals Thus, the less shielded d orbitals do not fill as readily as s orbitals with similar energy 16 D The electron configuration of rubidium is 2 2 6 2 6 2 10 6 1 ls 2s 2p 3s 3p 4s 3d 4p 5s This gives n = 5 and l = 0 for the last electron If l = 0 then ml must equal 0 The value of ms may be either +1 2 or 1 2 17 A Calcium will form a +2 ion (Ca2+), and X will need to gain two electrons to fill its outer 2 shell and become a 2 ion (X ) The simplest formula for a compound containing a +2 ion and a 2 ion would be CaX The other answers involve different charges or a formula that has not been simplified

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144 Liquid/Liquid Equilibrium (LLE)

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lower critical solution temperature (LCST); temperature Tu is an upper consolute temperature, or upper critical solution temperature (UCST) At temperatures between TL and Tu, LLE is possible; for T < TL and T > Tu, a single liquid phase is obtained for the full range of compositions The consolute points are analogous to the liquidlgas critical point of a pure fluid; they are limiting states of two-phase equilibrium for which all properties of the two equilibrium phases are identical Actually, the behavior shown on Fig 1412(a) is infrequently observed; the LLE binodal curves are often interrupted by curves for yet another phase transition When the binodal curves intersect the freezing curve, only a UCST can exist [Fig 1412(b)]; when they intersect the VLE bubblepoint curve, only an LCST can exist [Fig 1412(c)]; when they intersect both, no consolute point exists, and a fourth type of behavior is observed14 Thus it is apparent that real systems exhibit a diversity of LLE behavior The thermodynamic basis for calculation or correlation of LLE is an expression for G E / ~ ~ , from which activity coefficients are derived The suitability of a particular expression is determined by its ability to accommodate the various features illustrated by Fig 1412 This is a severe test, because, unlike their role in low-pressure VLE where they represent corrections to Raoult's law, the activity coefficients here are the only thermodynamic contribution to an LLE calculation

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